期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 117, 期 44, 页码 22887-22893出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp407348r
关键词
-
资金
- RFBR [11-03-00248-a, 12-03-00403-a, 12-03-31386-mol-a]
- RAS [5.1.1]
- SB RAS [60, 61, 57, 122]
- program of support of leading scientific schools [NSh-2429.2012.3]
- Council on Grants of the President of the Russian Federation [MK-4391.2013.3]
- Russian Government [11.G34.31.0045]
It is demonstrated that hyperpolarized catalyst-free gases can be produced in a gas-liquid biphasic hydrogenation with parahydrogen using a dissolved catalyst and gaseous reactants. The reaction product is shown to return to the gas phase while retaining a substantial level of nuclear spin hyperpolarization, providing a complete separation of the hyperpolarized substance from the catalyst. The approaches based on biphasic and heterogeneous hydrogenations are shown to be suitable for producing hyperpolarization in a continuous mode. Subsequent gas dissolution can be added to yield solutions of hyperpolarized substances. Extension to a broader range of hyperpolarized substances is shown to be possible based on the hydrogenation of liquid vapors.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据