期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 117, 期 3, 页码 1453-1456出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp305823u
关键词
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资金
- Weaving Science Web beyond Particle-Matter Hierarchy, Global Centers of Excellence program, Tohoku University
- World Premier International Research Center Initiative
- Special Coordination Funds for Promoting Science and Technology from the Ministry of Education, Culture, Sports, Science and Technology, Japan
- Grants-in-Aid for Scientific Research [24651128] Funding Source: KAKEN
Oxygen molecules are found to exhibit non-negligible reactivity with graphene under strong light irradiation in the presence of water. The reaction is triggered by the laser Raman spectroscopy measurement itself, and the D band (ca. 1340 cm(-1)) becomes larger as the laser irradiation is prolonged. The electronic transport properties of the graphene derivative are also investigated and both the electron and hole mobility are found to be reduced. These results are attributed to oxidation of graphene. This primitive modification method can be exploited to manipulate the structural and electronic properties of graphene.
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