期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 117, 期 13, 页码 6664-6668出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp312733t
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资金
- Funding Program for Next Generation World-Leading Researchers (NEXT Program) [GR-003]
New aluminum oxide clusters Al14O- and Al15O2- were observed unprecedentedly in the gas-phase reaction of Al-n(-) and O-2. Photoelectron spectroscopic measurements and density functional calculations indicated that Al14O- and Al15O2- are composed of an icosahedral Al-13 moiety bonded by one and two OAl unit(s), respectively. The preferential formation of Al14O- and Al15O2- is explained in terms of the high stability associated with the Al-13 moiety and efficient collisional trapping as intermediates of oxidative etching reactions.
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