期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 117, 期 19, 页码 9734-9738出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp311420d
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资金
- Deutsche Forschungsgemeinschaft [SFB 677]
- CALMIP [2012-P0686]
Ruthenium dyes (N3) are deposited by in situ ultrahigh vacuum (UHV) electrospray ionization on a Au(111) surface and investigated using scanning tunneling microscopy and spectroscopy. The molecules exhibit some fragmentation at deposition energies around 7 eV, while deposition of intact molecules is feasible with energies of 2.5 eV. A variety of adsorption geometries is found that are analyzed using spectroscopy of vibronic excitations and DFT calculations.
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