期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 116, 期 48, 页码 25376-25387出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp308453d
关键词
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资金
- Nagoya University
- [22-7799]
- Grants-in-Aid for Scientific Research [24656490] Funding Source: KAKEN
Direct aromatic ring hydroxylation of benzene derivatives by using water as an oxidant over platinum-loaded titanium oxide photocatalyst proceeded with high selectivity under the light of selected wavelength. Two kinds of electrophilic active species, which depended on the reaction condition, were proposed: a surface oxygen radical in neutral or acidic conditions and a hydroxyl radical in basic condition, both of which were produced by a photoformed hole on the surface of titanium oxide. In both cases, these active species can attack the aromatic ring to form an intermediate, followed by the formation of a hydroxylated product. Thus, the reaction proceeds through the addition-elimination mechanism. On the other hand, a photoformed electron reduces a proton to form a hydrogen radical, which reacts with the intermediate to produce a hydroxylated product and a molecular hydrogen or with another hydrogen radical to form a molecular hydrogen.
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