期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 116, 期 44, 页码 23629-23638出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp306452n
关键词
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资金
- National Natural Science Foundation of China [51173210, 51073177]
- Science and Technology Planning Project of Guangdong Province, China [2007A010500001-2, 2008B090500196]
- Construction Project for University-Industry cooperation platform for Flat Panel Display from the Commission of Economy and Informatization of Guangdong Province
- Fundamental Research Funds for the Central Universities
- Natural Science Foundation of Guangdong [S2011020001190]
Distyrylanthracene derivatives (AnPCz and AnPCz(3)) with monocarbazolyl and tricarbazolyl groups were synthesized and characterized via nuclear magnetic resonance, mass spectrometry, elemental analysis, photoluminescence, ultraviolet absorption, wide-angle X-ray diffraction, and other techniques. Another compound, distyrylanthracene (AnP), without any carbazolyl group was synthesized for comparison. The results show that the piezofluorochromic properties of the three aggregation-enhanced emission (AEE) compounds were significantly influenced by the variety of carbazolyl groups in the molecular structures. Compounds AnPCz and AnPCz(3) exhibited distinct piezofluorochromic properties and switched reversibly upon grinding-annealing or grinding-fuming. The piezofluorochromic activity can be greatly enhanced by the introduction of carbazole groups in the distyrylanthracene AEE structure. The general structure-property relationships established in this study will help researchers to identify and synthesize more piezofluorochromic materials.
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