期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 116, 期 21, 页码 11830-11836出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp303530h
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资金
- Academia Sinica (AS)
- National Science Council (NSC) of Taiwan [99-2221-E-001-002-MY3, 99-2113-M-001-023-MY3]
In this work, we investigated the temperature-dependent luminescence of bovine serum albumin-protected Au-25 nanoclusters and the correlation with their structure. Our experiments reveal that the red luminescence consists of two bands, namely, band I at 710 nm and band II at 640 nm. The temperature dependence of band I exhibits similarity to semiconductors, such as a red shift of emission and bandwidth broadening upon increasing temperatures due to electron-phonon and electron-defect/surface scattering. In contrast, band II exhibits different temperature dependence. It is concluded that band I exclusively originates from the icosahedral core of 13 Au(0) atoms and band H dominantly arises from the [-S-Au(I)-S-Au(I)-S] staples. Moreover, with increasing temperatures, the intensity of band I and band II decreases. A similar activation energy was extracted, which is attributed to thermally activated defect/surface trapping. In addition, the relaxation from band II to band I was found to be inactive from 300 K down to 77 K.
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