期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 116, 期 26, 页码 14078-14087出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp303164k
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资金
- Spanish Consolider Ingenio 2010 Program [CDS2007-00045]
- Spanish MICCIN [CTQ2009-I4596-C02-01, MAT2010-21270-C04-01/03/04]
- Comunidad de Madrid
- European Social Fund [S2009/PPQ-1551 4161893]
- Vicerrectorado de Investigacion de la Universitat Politecnica de Valencia [UPV2011-0914 PAID-05-11, UPV2011-0966 PAID-06-11]
We report X-ray diffraction measurements in CdIn2S4, MgIn2S4, and MnIn2S4 thiospinels at room temperature and high pressures. The pressure dependences of the structural parameters have been determined and compared to those from theoretical calculations. It is found that the three thiospinels have similar bulk moduli (B-0) between 75 and 80 GPa (B-0' similar to 3). The degree of inversion of these thiospinels has also been determined. The three thiospinels undergo a phase transition toward a defect LiTiO2-type structure above 9.5, 8.3, and 6.8 GPa in CdIn2S4, MgIn2S4, and MnIn2S4, respectively. Interestingly, the low- and high-pressure phases belong to the same symmetry group (Fd-3m), the transition mechanism being associated to the migration of the tetrahedrally coordinated cations to a Wyckoff position of higher multiplicity, where these cations present an octahedral environment. The new postspinel phase exhibits a larger compressibility than the spinel phase for the three compounds, likely due to the presence of stoichiometric vacancies in the unit cell as it occurs for defect chalcopyrites and stannites. The relation between the bulk and the polyhedral compressibilities is discussed as well.
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