Three-Dimentional Porous Nano-Ni/Co(OH)2 Nanoflake Composite Film: A Pseudocapacitive Material with Superior Performance

We report a novel three-dimentional (3D) porous nano-Ni/Co(OH)(2) nanoflake composite film electrode for potential supercapacitor applications with both high power and energy capabilities. The 3D porous nano-Ni film with highly porous nanoramified walls functions as a scaffold to anchor Co(OH)(2) nanoflakes to produce a 3D nanoporous metal/hydroxide nanoflake composite electrode. Co-(OH)(2) nanoflakes with thicknesses of 20 nm are directly electrodeposited on highly conductive 3D porous nano-Ni film prepared via a hydrogen bubble template. Impressively, the Co(OH)(2) nanoflake in the composite film exhibits a high specific capacitance of 1920 F g(-1) at 40 A g(-1), with a corresponding energy density as high as 80 W h kg(-1) at a power density of 11 kW kg(-1). Moreover, the designed composite film exhibits excellent cycling stability, making it one of the best electrode materials for high-performance supercapacitors. This work demonstrates that the 3D porous nanometal/hydroxide nanoflake composite approach is an effective strategy toward supercapacitors with high energy and power densities.