期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 115, 期 35, 页码 17479-17484出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp205069w
关键词
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资金
- Ministry of Education, China
- National Natural Science Foundation of China [NSFC-50878190]
- Science Foundation of Chinese University
- Natural Science Foundation of Zhejiang Province [Y5090053, Y5090163]
In this paper, a novel catalyst, titanate nanotube (TNT) confined CeO2 was designed and synthesized. Such catalyst showed a remarkable resistance to alkali metal poisoning in deNO(x) application. The catalyst effectively shielded the main active phase, CeO2, from the poisons with the tubular channel of H2Ti12O25. Furthermore, the poisons (e.g., Na+) could also be stabilized in the interlayer of H2Ti12O25 through ion exchange. This catalyst developed herein gives a new sight for the design of shell protection catalysts to improve their tolerance to poisons.
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