期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 115, 期 30, 页码 14834-14838出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp203129f
关键词
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资金
- National Research Foundation of Korea
- Ministry of Education Science and Technology of the Korean government [2005-2002369, 2007-0054038, 2010-0025301, 2010-0018781]
- Ministry of Education, Science and Technology of Korea [2010-0011085]
- National Research Foundation of Korea [2010-0011085, 2005-2002369, 2007-0054038, 2010-0018781] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Interchain interactions in arrays of metal-organic hybrid chains were studied using scanning tunneling microscopy and ab initio calculations. The array of hybrid chains having a Ag-anthryl biradical were self-assembled by catalytic scission of Br-C bonds in 9,10-dibromoanthracene on Ag(111). An atomic model for the observed chain structures was proposed. Ag atoms in chains were alternatingly located at hollow sites, making slightly zigzaging structures. Between the hybrid chains, Br atoms located at hollow sites to form Br center dot center dot center dot H intermolecular bonds. Anthryl biradicals had two different apparent heights; this was explained by considering Br center dot center dot center dot H intermolecular bonds and intrachain steric repulsion. When a hybrid chain was laterally moved by manipulation techniques, Br adsorbates moved together with the chain, implying that they are stabilized by Br center dot center dot center dot H intermolecular bonds.
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