期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 115, 期 11, 页码 4749-4756出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp111635t
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资金
- PRONEX
- LNLS (Campinas, Brazil) [D08B-XAFS2-8120]
- CNPq
- CAPES
In situ gallium K edge XAFS spectroscopy experiments were performed with GaZSM5 catalysts containing two different gallium loadings (2 and 4%) under hydrogen or propane in the 703-823K temperature range. It was found that, irrespective of the gallium loading and reducing gas, linear correlations were found between the coordination numbers of both the first (Ga-O scattering legs) and second (Ga-Ga scattering legs) gallium coordination spheres estimated from EXAFS and the degree of reduction estimated by XANES. The results showed that the reduction proceeds from Ga3+ binuclear species 4-fold coordinated to oxygen to an isolated Ga+ ion coordinated to a single oxygen atom.
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