期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 114, 期 14, 页码 6446-6451出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp100835b
关键词
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资金
- NSFC [20873031, 20833005]
- STCSM [08JC1402000, 08DZ2270500]
Inspired by the third-body effect and the d-band center theory, a series of carbon black-supported PdxPt1-x (denoted as PdxPt1-x/C, with atomic fraction x = 0 5-1) nanocatalysts were synthesized and screened in order to pinpoint the optimal composition targeted for the electrocatalytic oxidation of formic acid The effective alloying of these two elements is better demonstrated by the compositional dependent synergetic electrocatalysis identified for the as-synthesized PdxPt1-x/C nanoparticles rather than by the XRD characterization Preliminary screening indicates that Pd-0 Pt-9(0) (1)/C is the optimum catalyst for the desired reaction among all tested PdxPt1-x/C samples This high performance of the Pd-0 Pt-9(0) (1) nanoalloy can be ascribed to the effectively inhibited CO poisoning at largely separated Pt sites and appropriately lowered cl-band center of Pd sites.
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