期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 113, 期 29, 页码 12848-12853出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp9034166
关键词
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资金
- Science and Technology Commission of Shanghai Municipality [07JC14015]
- Shanghai Nanotechnology Promotion Centre [0752nm001]
- National Nature Science Foundation of China [20773039]
- National Basic Research Program of China [2007CB613301, 2004CB719500]
- Ministry of Science and Technology of China [2006AA06Z379, 2006DFA52710]
A simple method to prepare the N-TiO2 adsorbed with Fe3+ ions only on the surface of catalysts and modify the catalysts by a redox treatment (NaBH4 reduction and air oxidation treatment) was proposed. The samples were characterized by X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy, FTIR, X-ray photoelectron spectroscopy (XPS), and high-resolution transmission electron micrograph (HRTEM). The photocatalytic activities of the samples were evaluated for degradation of methylene blue (MB) in aqueous solutions under visible light (lambda > 420 nm). The results of XRD, FTIR, XPS, and HRTEM analysis indicated that the structure of Fe compounds changed from Fe2O3 to gamma-FeOOH after redox treatment. Compared to N-TiO2 with Fe3+ ions, the catalysts after redox treatment showed higher photoactivity under visible light, and the formation of gamma-FeOOH was responsible for the improvement of photocatalytic activity. Furthermore, to the catalysts after redox treatment, the mechanism for degradation of MB under visible light is an opening of a central aromatic ring attacked by OH center dot combined with a process of gamma-FeOOH photoreductive dissolution.
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