期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 112, 期 24, 页码 8747-8750出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp802627s
关键词
-
A self-consistent band theory has been developed for electrochemical interfaces. The surface potential is adjustable by adding surface charge, and a counter charge distribution in the double layer is determined self-consistently using a modified Poisson-Boltzmann theory within a dielectric continuum model. We demonstrate a theory to predict, to useful accuracy, the reversible potentials for 34 acid or base aqueous phase reactions and 4 reactions that are key to understanding electrocatalysis by platinum in oxygen cathodes in fuel cells. We believe this theory will find many applications.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据