期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 112, 期 22, 页码 8429-8437出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp800298b
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The synthesis and optical properties of a series of alkoxyphenyl-pyridyl butadiene derivatives in solution and in the solid state are described. All the derivatives were practically nonfluorescent in solution but showed good fluorescence in the solid-state. The role of molecular packing in controlling the solid-state fluorescence. was investigated by studying the X-ray crystal structure of these molecules. One of the derivatives, 4-((1E,3E)-4-(4-butoxyphenyl)buta-1,3-dienyl)pyridine exhibited polymorphism, with the different polymorphs exhibiting visually distinguishable fluorescence. In the natural state it existed as a polymorph exhibiting blue fluorescence, while it's cooled melt emitted yellow light. The difference could be attributed to a transformation in the molecular packing of the material from a herringbone to a brickstone arrangement, resulting in a change from monomer to J-type aggregate fluorescence. The polymorph exhibiting yellow fluorescence. was fairly stable (>6 months) but could be converted back to the original form by keeping the film at 110 degrees C for a short period of time (similar to 8-10 min) before slowly cooling to room temperature. The thermally induced changes in fluorescence behavior were clearly reproducible over several cycles, indicating the utility of this material for thermal imaging applications.
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