期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 112, 期 5, 页码 1308-1311出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp711191j
关键词
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Multistep surface processes involving a number of association reactions and desorption processes may be considered as hypothetical one-step desorption processes. Thus, heterogeneous catalytic reactions can be treated kinetically as consisting of two steps: adsorption and desorption. It is also illustrated that the hypothetical one-step desorption process follows the BEP relation. A volcano curve can be obtained from kinetic analysis by including both adsorption and desorption processes.
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