期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 112, 期 37, 页码 14236-14240出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp801343y
关键词
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资金
- Office of Basic Energy Sciences
- Division of Materials Science and Engineering Physics
- U.S. Department of Energy [DE-AC06-76RL0 1830]
Colloidal carbon spheres have been prepared from aqueous alpha-, beta-, and gamma-cyclodextrin (CD) solutions in closed systems under hydrothermal conditions at 160 degrees C. Both liquid and solid-state C-13 NMR spectra taken for samples at different reaction times have been used to monitor the dehydration and carbonization pathways. CD slowly hydrolyzes to glucose and forms 5-hydroxymethyl furfural (HMF) followed by carbonization into colloidal carbon spheres. The isolated carbon spheres are 70-150 nm in diameter, exhibit a core-shell structure, and are comprised of a condensed core (C=C) peppered with resident chemical functionalities including carboxylate and hydroxyl groups. Evidence from C-13 solid-state NMR and FT-IR spectra reveal that the evolving carbon spheres show a gradual increase in the amount of aromatic carbon as a function of reaction time and that the carbon spheres generated from gamma-CD, contain significantly higher aromatic carbon than those derived from alpha- and beta-CD.
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