期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 117, 期 27, 页码 8293-8299出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp405480h
关键词
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资金
- Japan Society for the Promotion of Science (JSPS) [22350056]
- Grants-in-Aid for Scientific Research [22350056] Funding Source: KAKEN
Thermodynamic and diffraction analyses were performed to establish the phase diagram for a binary system between 4-n-nonyl-4'-isothiocyanatobiphenyl (9TCB) and n-nonane. The swollen SmE structure is identified in the binary system. Upon swelling : a characteristic two-dimensional herringbone array is Maintained whereas the layer spacing of SmE structure increases with the content of n-nonane. Considering the difficulties in explaining the experimental findings based on the traditional model of SmE structure,, a new model lamellar with two types of sublayers consisting of aromatic core and chain moieties, is proposed.
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