期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 117, 期 32, 页码 9540-9547出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp404053t
关键词
-
资金
- MIUR-PRIN
- [ERC-226207-PATCHYCOL-LOIDS]
- [ITN-234810-COMPLOIDS]
We numerically calculate the equilibrium phase diagram of one-patch particles with 30% patch coverage. It has been previously shown that in the fluid phase these particles organize into extremely long tubelike aggregates (G. Munao et al. Soft Matter 2013, 9, 2652). Here, we demonstrate by means of free-energy calculations that such a disordered tube phase, despite forming spontaneously from the fluid phase below a density-dependent temperature, is always metastable against a lamellar crystal. We also show that a crystal of infinitely long packed tubes is thermodynamically stable, but only at high pressure. The full phase diagram of the model, beside the fluid phase, displays four different stable crystals. A gas-liquid critical point, and hence a liquid phase, is not detected.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据