期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 117, 期 31, 页码 9170-9181出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp403872a
关键词
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资金
- Ministerio de Economia y Competitividad [MAT2011-27225]
- Generalitat de Catalunya through the Grup Consolidat [SGR 2009 1307]
- Ministerio de Educacion through Factoria Cristalografica [Consolider-Ingenio CSD2006-15]
- Ministerio de Educacion through Beca del Programa de Formacion de Profesorado Universitario (FPU)
This study examined the influence of different thermal treatments on the crystallization and transformation of trioleoyl glycerol (OOO) and 1,2-dioleoyl-3-rac-linoleoyl glycerol (OOL). Two triacylglycerol (TAG) samples were cooled at 0.5-15 degrees C.min(-1) and heated at 2 and 15 degrees C-min(-1). The polymorphic characteristics of the two TAGs were analyzed in situ using differential scanning calorimetry, Raman spectroscopy, and synchrotron radiation X-ray diffraction. Multiple polymorphic forms were identified in OOO (alpha, beta(2)', beta'(1), beta(2)', and beta(1)) and OOL (alpha, beta(2)', and beta'(1)). Larger quantities of more stable forms (e.g., beta(2) and beta(1) of OOO and beta'(1) of OOL) were obtained when the samples were slowly cooled and heated. In contrast, less stable polymorphs were obtained with increased cooling and heating rates. Polymorphic transformations occurred in either solid-state or melt-mediation and were influenced by heating rates. The results were analyzed by considering the activation energies for crystallization and transformation of stable and less stable polymorphic forms in comparison with previous studies on 1,3-dipalmitoyl-2-oleoyl-glycerol glycerol.
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