期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 116, 期 6, 页码 1858-1864出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp211543v
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资金
- University of Sydney
The ability of a binary ionic liquid (IL) system consisting of a phosphonium transition state analogue (TSA) and 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([BMIM][NTf2]) to accelerate the rate of the well-studied hydrolysis. of a tert-alkyl picolinium salt by influencing the solvent structure was investigated. A significant rate enhancement was observed in the presence of the TSA; however, comparison with other cations illustrated that this enhancement was not unique to the chosen TSA. Instead, the rate enhancements were correlated with the dilution of hydrogen bonding by the added cations. This phenomenon was further examined by the use of 1-butyl-2,3-dimethylimidazolium bis(trifluoromethanesulfonyl)imide ([BMMIM][NTf2]) as a cosolvent and the use of Reichardt's dye to measure the extent of hydrogen bonding on solutes in these systems. The rate increases are rationalized in terms of weaker hydrogen bonding from the solvent system to water.
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