期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 114, 期 45, 页码 14696-14702出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp102901u
关键词
-
资金
- Department of Energy [DE SC0001517]
- NSF MRSEC [DMR0520020]
- DOE EFRC [P353 0127]
- Carolyn Hoff Lynch Graduate Fellowship
- Francqui Foundation (Belgium)
- VLAC (Vlaams Academisch Centrum)
- Centre for Advanced Studies of the Royal Flemish Academy of Belgium for Science and the Arts
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0923097] Funding Source: National Science Foundation
- U.S. Department of Energy (DOE) [DE-SC0001517] Funding Source: U.S. Department of Energy (DOE)
Transient dynamical studies of bis[(5 5`-10,20-bis(2,6-bis(3,3-dimethylbutoxy)phenyl)porphinato)palladium(II)] ethyne (PPd2), 5,15-bis{[(5`-10,20-bis(2,6-bis(3,3-dimethylbutoxy)phenyl)porphinato)palladium(II))ethynyl} (10,20-bis(2 6-bis(3 3-dimethylbutoxy)phenyl)porphinato)palladium(I) (PPd3), bis[(5,5`-10,20-bis(2,6-bis(3 3-dimethylbutoxy)phenyl)porphinato)platinum(II)ethyne (PPt2), and 5,15-bis {[(5`-10,20-bis(2,6-bis(3,3-dimethylbutoxy)phenyl)porphinato)platinum(II)]ethynyl} (10 20-bis(2,6-bis(3,3-dimethylbutoxy)phenyl)porphinato)platinum(II) (PPt3) show that the electronically excited triplet states of these highly conjugated supermolecular chromophores can be produced at unit quantum yield via fast S-1 -> T-1 intersystem crossing dynamics (tau(isc) 5 2-49 4 ps) These species manifest high oscillator strength T-1 -> T-n transitions over broad NW spectral windows The facts that (i) the electronically excited triplet lifetimes of these PPdn and PPtn, chromophores are long, ranging from 5 to 50 mu s and (ii) the ground and electronically excited absorptive manifolds of these multipigment ensembles can be extensively modulated over broad spectral domains indicate that these structures define a new precedent for conjugated materials featuring low-lying pi-pi* electronically excited states for NIR optical limiting and related long-wavelength nonlinear optical (NLO) applications
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据