期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 114, 期 34, 页码 11149-11154出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp105317e
关键词
-
The electrical double-layer structure and capacitance in room temperature ionic liquids at electrified interfaces were systematically studied with use of the self-consistent mean-field theory The capacitance curve departs from symmetry with respect to the point of zero charge when unequal ion-size is implemented or when specific adsorption of ions is introduced For the case of unequal ion-size, the shape of the capacitance curve is strongly determined by the size of the counterion and only weakly influenced by the co-ion size. When present, specifically adsorbed ions would change the capacitance within a limited range of applied potential from the point of zero charge, which itself vanes with the strength of specific adsorption
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据