No Charge Reversal at Foam Film Surfaces after Addition of Oppositely Charged Polyelectrolytes?

The present work deals with control of the stability of ionic surfactant (tetradecyl trimethyl ammonium bromide) foam films by the addition of oppositely charged polyelectrolytes. In the two cases of low and high polyelectrolyte concentrations, a common black film is formed. This is due to an electrostatic repulsion (in the latter case, according to the hitherto assumption) caused by a charge reversal at film surfaces at high polyelectrolyte concentration. But what happens around the nominal isoelectric point (IEP), where the net charge of the whole film is close to zero? Is a Newton black film formed or does the film break? Disjoining pressure isotherms show a strong reduction in stability close to the IEP. The comparison between surface tension and elasticity measurements and disjoining pressure isotherms leads to a surprising conclusion: The stability of foam films seems not to be dominated by the net charge of the polyelectrolyte/surfactant complexes at the surface, which was the former hypothesis, but by the overall net charge of the film.