期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 113, 期 28, 页码 9493-9498出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp9034369
关键词
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资金
- Natural Sciences and Engineering Research Council of Canada
- Fonds Quebecois de la Recherche stir la Nature et les Technologies
- Canada Foundation for Innovation
- Universite de Montreal
The binding interactions between cucurbit[7]uril (CB[7]) and different polyimidazolium cations containing aromatic binding sites (1,4-xylylene units) were studied experimentally by 1D and 2D NMR, high-resolution mass spectrometry (HRMS), and fluorimetry, and, theoretically, by computed geometries and enthalpy changes. CB[7] was found to form [2]- and [3]-pseudorotaxanes with these cations by the inclusion of the internal 1,4-xylylene units.
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