期刊
JOURNAL OF PHYSICAL CHEMISTRY B
卷 113, 期 11, 页码 3333-3338出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp8089775
关键词
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资金
- National Natural Science Foundation of China [20874099]
- Creative Research Groups [50621302]
- Outstanding Young Investigators [50725312]
- National Basic Research Program of China [2007CB808000]
Novel bump-surface multicompartment micelles formed by a linear amphiphilic ABC triblock copolymer via self-assembly in selective solvent were successfully observed both in simulation and experiment. The results revealed that the block A forms the most inner core, and the blocks B and C form the inner and outer layers, respectively, and the bumps were formed by block A and more likely to be born on curving surfaces. Moreover, the micelle shape could be controlled by changing the solvent selectivity of the blocks A and B. Spherical, cylindrical, and discoidal micelles with bumpy surfaces were obtained both in experiment and simulation.
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