期刊
JOURNAL OF PHYSICAL CHEMISTRY A
卷 116, 期 46, 页码 11219-11227出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp3052054
关键词
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资金
- Institute of Advanced Energy, Kyoto University [B-22]
- [23550004]
- Grants-in-Aid for Scientific Research [23550004] Funding Source: KAKEN
Nonresonant optimal control simulation is applied to a CO molecule to design two-color phase-locked laser pulses (800 nm + 400 nm) with the aim of orienting the molecule under the field free condition. The optimal pulse consists of two subpulses: the first subpulse aligns the molecule and the second one orients it. The molecular alignment induced by the first subpulse considerably enhances degree of orientation, the value of which is close to an ideal value at temperature T = 0. K. To confirm the effectiveness of this alignment enhanced orientation mechanism, we adopt a set of model Gaussian pulses and calculate the maximum degrees of orientation as a function of the delay time and the intensity. In finite temperature (T = 3.0 K and T = 5.0 K) cases, although the alignment subpulse can improve the degree of orientation, the control achievement. decreases with temperature rapidly, this decrease Can be attributed to the initial-state-dependent (phase shifted) rotational wave packet motion.
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