期刊
JOURNAL OF PHYSICAL CHEMISTRY A
卷 116, 期 48, 页码 11905-11912出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp310171r
关键词
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资金
- Universite de Lorraine et CNRS
- CNRS
We report the time-dependent density functional theory study of the absorption spectrum of an iron complex exhibiting photoisomerization properties. The role of the exchange-correlation functionals and, in particular, the effects of the inclusion of long-range corrections have been considered. The vertical transitions have been analyzed in terms of natural transition orbitals and have shown that the spectrum is dominated by ligand-to-metal charge-transfer transitions, an occurrence that could be promising for future applications of these complexes.
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