4.6 Article

Surface Deposition and Imaging of Large Ag Clusters Formed in He Droplets

期刊

JOURNAL OF PHYSICAL CHEMISTRY A
卷 115, 期 25, 页码 7199-7204

出版社

AMER CHEMICAL SOC
DOI: 10.1021/jp200198n

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  1. NSF [CHE 0809093]
  2. Direct For Mathematical & Physical Scien
  3. Division Of Chemistry [1112391] Funding Source: National Science Foundation
  4. Direct For Mathematical & Physical Scien
  5. Division Of Chemistry [809093] Funding Source: National Science Foundation

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The utility of a continuous beam of He droplets for the assembly and surface deposition of Ag-N clusters, < N > similar to 300-6000, is studied with transmission electron microscopy. Images of the clusters on amorphous carbon substrates obtained at short deposition times have provided for a measure of the size distribution of the metal clusters. The average sizes of the deposited clusters are in good agreement with an energy balance based estimate of AgN cluster growth in He droplets. Measurements of the deposition rate indicate that upon impact with the surface the He-embedded cluster is attached with high probability. The stability of the deposited clusters on the substrate is discussed.

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