期刊
JOURNAL OF PHYSICAL CHEMISTRY A
卷 115, 期 5, 页码 643-647出版社
AMER CHEMICAL SOC
DOI: 10.1021/jp106115d
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资金
- Grants-in-Aid for Scientific Research [21254006] Funding Source: KAKEN
Experimental NMR measurements for C-13 chemical shifts of propane molecules encaged in 16-hedral cages of structure II clathrate hydrate were conducted to investigate the effects of guest-host interaction of pure propane clathrate on the C-13 chemical shifts of propane guests. Experimental C-13 NMR measurerments revealed that the clathrate hydration of propane reverses the C-13 chemical shifts of methyl and methylene carbons in propane guests to gaseous propane at room temperature and atmospheric pressure or isolated propane, suggesting a change in magnetic environment around the propane guest by the clathrate hydration. Inversion of the C-13 chemical shifts of propane clathrate suggests that the deshielding effect of the water cage on the methyl carbons of the propane molecule encaged in the 16-hedral cage is greater than that on its methylene carbon.
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