期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS
卷 9, 期 4, 页码 157-170出版社
ELSEVIER
DOI: 10.1016/j.jphotochemrev.2008.05.001
关键词
Titanium dioxide; Titanium oxide; Photocatalysts; Selective organic transformation; Organic synthesis; Gas phase reaction; Liquid phase reaction; One-pot reaction
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT) [19760536, 20360359]
- Grants-in-Aid for Scientific Research [20360359] Funding Source: KAKEN
This article reviews recent advances in selective organic transformations, both in gas and liquid media, using titanium oxide-based photocatalysts. Several photocatalytic reactions, such as oxidation, reduction, and Coupling reactions, proceed highly efficiently and selectively without requiring harmful and dangerous chemical reagents and without harmful byproducts. In addition, multistep processes usually required for conventional synthesis of various kinds of valuable compounds can be simplified to a one-pot reaction when in photocatalytic systems. Photocatalytic transformations will therefore play a very important role for organic synthesis in an economically and environmentally friendly way. This review article demonstrates that titanium oxide-based photocatalysts have a great potential as a versatile tool in green organic synthesis. (c) 2008 Elsevier B,V. All rights reserved.
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