期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 272, 期 -, 页码 1-5出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2013.08.021
关键词
Photocatalysis; C-C coupling reaction; Pinacol; Titania; Structure modulation; Calcination
资金
- New Staff Start-up Research Fund from School of Chemical and Biological Engineering, Taiyuan University of Science and Technology
- Monash University
Aliphatic pinacol (C-6) was prepared for the first time by photocatalytic C-C coupling of isopropanol in an aqueous solution at room temperature by using Pt/TiO2 catalyst. The phase and pore structure of TiO2 was modulated by calcination of the commercial TiO2 at 500-900 degrees C. High isopropanol conversion was achieved when the commercial P25 TiO2 was calcined at 600 degrees C for 20h, and the highest pinacol yield was of 14.7% at the photocatalytic reaction of 20 h. (C) 2013 Elsevier B.V. All rights reserved.
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