Photodegradation kinetics of 2,6-dimetylphenol by natural iron oxide and oxalate in aqueous solution

Heterogeneous photodegradation of 2,6-dimethylphenol (2,6-DMP) in the natural iron oxide (NIO) system with oxalic acid under UV irradiation was investigated. The NIO was characterized by X-ray diffraction (XRD), X-ray fluorescence and Brunauer-Emmett-Teller (BET) methods. The XRD pattern of NIO showed a mixed crystal structure. In order to show the effect of temperature on the structure of NIO, the last one was calcined at 800 degrees C and 1000 degrees C. The XRD patterns of calcined iron oxides at 800 degrees C (NIO/800) and 1000 degrees C (NIO/1000) depict the conversion from mixed crystalline hematite to completely pure crystalline hematite. The experiments showed that the most effective catalyst for degradation of 2,6-DMP is NIO in presence of oxalate. The dependence of 2,6-DMP degradation was attributable to the formation of the dissolved Fe-oxalate in the solution and the adsorbed Fe-oxalate on the surface of natural iron oxide. The photodegradation of 2,6-DMP depends also on the oxalate and pH. The optimal initial concentration of oxalic acid was found to be 5 x 10(-3) M. The results demonstrated that the optimal pH value should be in the range of 3-4. The use of 2.0% of isopropanol as a scavenger confirmed the intervention of hydroxyl radicals in the photodegradation of 2,6-DMP. Furthermore, an important effect of oxygen was observed. (C) 2012 Elsevier B.V. All rights reserved.