期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 220, 期 2-3, 页码 134-138出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2011.04.003
关键词
Axial chirality; Binaphthyl; Circular dichroism (CD); Circularly polarized luminescence (CPL); Fluorescence
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [22750133]
- TEPCO Research Foundation
- JSPS
- Grants-in-Aid for Scientific Research [22750133, 10J00653] Funding Source: KAKEN
It is important to first determine the solid-state chiral optical properties of basic fluorescence supramolecular building blocks that can form a network structure via intermolecular interactions. Although the circularly polarized luminescence (CPL) properties of (R)-1,1'-binaphthyl-2,2'-dicarboxylic acid with axial chirality could not be measured in either the solution or solid states, those of (R)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate with axial chirality were successfully measured in both states. The solid-state CPL originates from the intramolecular interaction of single molecule, rather than intermolecular interactions in the crystal. (C) 2011 Elsevier B.V. All rights reserved.
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