期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 206, 期 2-3, 页码 109-115出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2009.05.022
关键词
Photoswitch; Spiropyran; Photodegradation; Surface immobilization; Sensor; Light-modulation; Molecular modelling
资金
- Enterprise Ireland [07/RFP/MASF812]
- Science Foundation Ireland [07/CE/11147]
- DCU Research Career Start Fellowship
- Science Foundation Ireland (SFI) [07/RFP/MASF812] Funding Source: Science Foundation Ireland (SFI)
Switchable materials have tremendous potential for application in sensor development that could be applied to many fields. We are focusing on emerging area of wireless sensor networks due to the potential impact of this concept in society. Spiropyran-based sensors are probably the most studied type of photoswitchable sensing devices. They suffer from many issues but photofatigue, insufficient selectivity and lack of sensitivity are probably the most important characteristics that hinder their wider application. Here, we are address these issues and demonstrate that covalent attachment of modified spiropyran into a polymeric film significantly reduces photodegradation. The observed signal loss after 12th cycle of switching between the spiropyran and merocyanine forms is only about 27% compared to the loss of 57% of the initial signal in an equivalent experiment based on non-immobilized spiropyran. This has enabled us to demonstrate at least five reversible cycles of detection of an ion of interest (in our case H+) with minimal signal loss. Furthermore, we demonstrate that the sensitivity can be increased by incorporation of additional binding groups in the parent spiropyran molecule. Using molecular modelling to calculate the relevant bond lengths as a measure of interaction between MC and H+, the calculated increase of H-bond strength is approximately an order of magnitude for a derivative containing a methoxy group incorporated in the o-position of the parent spiropyran in comparison to the equivalent unsubstituted phenol. This theoretical result was found to correspond very well with experimental observation. As a result, we have increased the sensitivity to H+ by approximately one order of magnitude. (C) 2009 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据