期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 201, 期 2-3, 页码 128-135出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2008.10.003
关键词
Benzoporphyrin; Phosphorescence; Metal complex; Oxygen quenching
资金
- European Commission [EU 506965]
New platinum(II) and palladium(II) complexes with fluorinated benzoporphyrins are prepared and characterized. The photo-physical and electrochemical properties, as well as quenching by oxygen are investigated. The complexes possess highly efficient room-temperature NIR phosphorescence and are excitable with blue- and red-light. The fluorinated derivatives show improved photo-physical properties and photo-stability. The new dyes are particularly suitable as indicators for the use in optical oxygen sensors. (c) 2008 Elsevier B.V. All rights reserved.
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