期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 706, 期 -, 页码 99-105出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2012.02.007
关键词
Amination; Cross-coupling; Halide; Palladium; Phosphine
资金
- National Natural Science Foundation of China [21072071]
- Science Foundation of Central China Normal University
2-Mesitylindenyl phosphine ligand (1) and [(2-mesitylindenyl)dicyclohexyl-phosphine]PdCl2 (2) have been synthesized and fully characterized by NMR and elemental analysis, as well as by X-ray crystallography for 2. A Highly active catalyst system derived from a palladium precatalyst and bulky 2-mesitylindenyl phosphine ligand (1) for the Buchwald-Hartwig amination reaction of aryl halides with primary and secondary amines has been developed. This method allows for the preparation of a wide variety of amines in moderate to excellent yields and displays a high level of activity for the coupling of aryl chlorides as well as hindered aryl bromides. (C) 2012 Elsevier B. V. All rights reserved.
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