期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 696, 期 1, 页码 46-49出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2010.07.015
关键词
Palladium; Alcohol oxidation; Hydroamination; Styrene
资金
- Chinese Academy of Science
- National Natural Science Foundation of China [20821002, 20872155, 20972175, 20923005]
- National Basic Research Program of China [973-2009CB825300]
- STCSM [08PJ1411600, 08dj1400100]
Palladium-catalyzed inter- and intramolecular hydroaminations of styrenes that are coupled to alcohol oxidation under oxidative condition are reported. The fluorination reagent NFSI is used as the nitrogen source as well as the oxidant. Bidental nitrogen ligand bathocuproine plays a crucial role in this transformation. (C) 2010 Elsevier B.V. All rights reserved.
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