期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 696, 期 17, 页码 2928-2934出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2011.04.031
关键词
Suzuki cross-coupling; Palladium; Ferrocenyl; Phosphine
资金
- Ministry of Education of Singapore
- National University of Singapore [C-143-000-003-001, R-143-000-259-112]
A mixture of Pd-2(dba)(3)/{eta-C5H4CH=N[CH(CH3)(Nap)]}Fe[eta-C5H4P(Bu-t)(2)] efficiently catalyzes the Suzuki reactions of a variety of bulky aryl halides and aryl- and alkyl-boronic acids, affording the desired cross-coupling biaryl products in quantitative isolated yields under mild conditions and at low (1 x 10(-6) -1 mol%) Pd loadings. Spectroscopic (NMR & ESI) analysis of the mixture of Pd-2(dba)(3), the hybrid [P,N] ligands, and aryl halides revealed different structural forms of oxidative addition products that are dependent on the substituent on the imino nitrogen. (C) 2011 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据