期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 696, 期 9, 页码 1916-1919出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2011.02.014
关键词
Lanthanum metal; FBW rearrangement; Alkynes; gem-Dihaloalkenes
资金
- Ministry of Education, Culture Sports, Science and Technology of Japan
The first example of the FBW rearrangement using of lanthanum metal and a catalytic amount of iodine was disclosed. When gem-diiodo-and gem-dibromoalkenes were treated with lanthanum metal in the presence of a catalytic amount of iodine, the reductive dehalogenation of these compounds smoothly proceeded to produce the corresponding alkynes in moderate to good yields. (C) 2011 Elsevier B.V. All rights reserved.
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