期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 695, 期 4, 页码 630-633出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2009.11.020
关键词
Ruthenium(II); Schiff base; Carbonyl; Redox properties; Crystal structures; C-H center dot center dot center dot pi interaction
资金
- Department of Science and Technology (DST) [SR/S1/IC-10/2007]
- Council of Scientific and Industrial research
Reactions of [Ru(PPh3)(3)Cl-2] with 2-(benzylimino-methyl)-4-R-phenol ((HL)-L-R, R = H, Cl, Br and OMe) in boiling methanol in presence of triethylamine afford ruthenium(II) complexes of general formula [Ru(L-R)(PPh3)(2)(CO)Cl] in 57-64% yield. Microanalysis, spectroscopic (infrared, electronic and NMR) and cyclic voltammetric measurements have been used for the characterization of the complexes. Crystal structures of two representative complexes have been determined by X-ray crystallography. The carbonyl, the chloride, the N,O-donor L-R and the two mutually trans PPh3 molecules assemble a distorted octahedral CClNOP2 coordination sphere around the metal centre in each complex. The complexes display the Ru(II) -> Ru(III) oxidation in the potential range 0.62-1.16 V (vs. Ag/AgCl). (C) 2009 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据