期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 694, 期 22, 页码 3559-3564出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2009.07.018
关键词
Crystal structure; Mannich; Three-component reaction; Organobismuth; Perfluorooctanesulfonate
资金
- National Science Foundation of China [20507005, 20873038, E50725825]
- 11th Five-Year Plan of Hunan Province
- Hong Kong Baptist University [FRG/08-09/II-09]
An air-stable hypervalent organobismuth (III) perfluorooctanesulfonate was synthesized and characterized by spectroscopic and X-ray crystallographic techniques, and found to exhibit high catalytic efficiency towards one-pot Mannich-type reaction of ketones with aromatic aldehydes and aromatic amines in water. This catalyst also shows good recyclability and reusability. This catalytic system would provide a simple, efficient and 'green' avenue towards the synthesis of beta-amino ketones. (C) 2009 Published by Elsevier B.V.
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