期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 693, 期 15, 页码 2499-2508出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2008.04.044
关键词
non-symmetric bis(thiazoline) ligands; oxazoline-thiazoline ligands; asymmetric allylic substitution; palladium complexes; quantum chemical calculations
New thiazoline-containing ligands including non-symmetric bis(thiazolines) and oxazoline-thiazolines were synthesized and then compared to C-2-symmetric bis(thiazolines) in the palladium-catalyzed allylic substitution. The experimental results obtained in this study support the hypothesis of a competition between the (N,N) and the (N,S) palladium chelation, when sterically hindered bis(thiazolines) are used as ligands. A quantum chemical study performed on the Pd-complexes derived from three selected ligands, two C-2-symmetric bis(thiazolines) and one oxazoline-thiazoline, also supports this hypothesis. (C) 2008 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据