期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 83, 期 18, 页码 11392-11398出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01635
关键词
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资金
- SERB-DST [EMR/2016/001643]
- CSIR-New Delhi (CSIR-SRF)
Diacetoxyiodobenzene-mediated remote hydroxylation of 8-aminoquinoline amide at the C-5 position has been developed. Various aryl, heteroaryl, and aliphatic carboxamides work well to afford the hydroxylated derivatives in good yields. This protocol is scalable and exhibits high functional group tolerance. Experimental results suggest that the reaction likely proceeds through the single-electron-transfer pathway.
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