期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 83, 期 19, 页码 12044-12055出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01994
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资金
- UCLouvain
- University of Greenwich
Disubstituted malonic acid derivatives are smoothly converted into diketones and ketoesters in good to excellent yield (68% to 91%) under electrochemical conditions. The scope can be extended to transform trisubstituted bis-malonic acids into tetraketones in 77% to 86% yield. The new method was applied to the total synthesis of cis-jasmone.
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