4.7 Article

D-A-D Structured Bis-acylhydrazone Exhibiting Aggregation-Induced Emission, Mechanochromic Luminescence, and AI(III) Detection

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JOURNAL OF ORGANIC CHEMISTRY
卷 83, 期 18, 页码 10770-10775

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AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b01377

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资金

  1. SERB, New Delhi, India [YSS/2015/000037, SR/S2/RJN-62/2012]
  2. UGC, New Delhi
  3. UGC FRP faculty award [F.4-5(94-FRP)/2014(BSR)]

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A readily accessible D-A-D triad molecule 1 was synthesized through acylhydrazone bond formation using carefully chosen building blocks. The molecule 1 exhibits emission through charge-coupled proton transfer and enhanced emission induced through aggregation and mechanochromic luminescence. Further, it detects Al(III) selectively among other cations in an efficient manner.

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