期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 83, 期 22, 页码 13625-13635出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b02025
关键词
-
资金
- Japan Society for the Promotion of Science (JSPS) [17K05779]
Two types of photoreactions between electronically differentiated donor and acceptor alkenes assisted by nucleophilic addition using an organic photoredox catalyst efficiently afforded 1:1 or 2:1 cross-coupling adducts. A variety of alkenes and alcohols were employed in the photoreaction. Control of the reaction pathway (i.e., the formation of the 1:1 or 2:1 adduct) was achieved by varying the concentration of the alcohol used. Detailed mechanistic studies suggested that the organic photoredox catalyst acts as an effective electron mediator to promote the formation of the cross-coupling adducts.
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