期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 19, 页码 9319-9324出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo501894j
关键词
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资金
- National Science Foundation of China [21172199]
- Natural Science Foundation of Zhejiang Province [LR12B02001, LY14B020002]
- Zhejiang Normal University
A Pd-catalyzed, highly regio- and stereoselective addition of boronic acids to ynamides has been realized. This protocol generates (Z)-alpha,beta-disubstituted enamides in high yields with excellent regio- and stereoselectivity under the mild reaction conditions, thereby providing a good complementary method for the diverse synthesis of multifunctional enamides. A wide collection of functional groups are found to be tolerated. It represents a straightforward and useful means to assemble stereodefined enamides from readily available starting materials.
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