期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 79, 期 20, 页码 9899-9906出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo501995c
关键词
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资金
- Institute for Basic Science (IBS)
- Ministry of Science, ICT & Future Planning, Republic of Korea [IBS-R010-D1-2014-A00] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Quinoline N-oxides were found to undergo Cp*Rh(III)-catalyzed coupling with internal diarylalkynes to provide 8-functionalized quinolines through a cascade process that involves remote C-H bond activation, alkyne insertion, and intramolecular oxygen atom transfer. In this reaction, the N-oxide plays a dual role, acting as a traceless directing group as well as a source of oxygen atom, as confirmed by an O-18-labeling experiment.
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